Zheng, X., Chen, W., Wang, G., Yu, Y., Qin, S., Fang, J., ... & Zhang, X. A. (2015). AIP Advances, 5(5).
Raman spectroscopy was employed to study the interaction between graphene and gold nanoparticles (GNPs). Various structures of graphene combined with GNPs were prepared, including single-layer transferred pure graphene (G1), three-layer stacked graphene (G3), a composite structure of GNPs deposited on G1 (G1/GNPs), and a sandwich structure consisting of three layers of graphene and two layers of GNPs.
G1 and G3 were prepared by transferring graphene onto a quartz substrate using the thermal release tape method once and three times, respectively. Figures (a) to (d) illustrate the transfer process. First, the peelable tape is placed on top of the graphene/Cu substrate, and then the stacked tape/graphene/Cu substrate is immersed in a ferric chloride solution. After etching the Cu substrate with the ferric chloride solution, the tape/graphene film is placed onto the quartz substrate. By heating the substrate to 120 °C, the thermal release tape is released, leaving the graphene on the quartz, completing the transfer for sample G1. Sample G3 was prepared by repeating the process shown in figures (a) to (d) and transferring the graphene onto the same quartz substrate three times. G1/GNPs was prepared by transferring the graphene onto quartz once, followed by dropping the GNPs solution onto the surface and allowing it to dry naturally at room temperature. The "sandwich" sample was prepared by alternately transferring graphene and depositing GNPs using the methods mentioned above. Figures (e), (f), and (g) depict the structures of G1/GNPs, the sandwich, and G3, respectively.